debug version works release version doesn't

In developing my project I've come to a point where the x64 Debug version works and it works great. But the x64 Release version launches and then gives me a message saying my application has stopped working and it doesn't resume. I've compiled both with all the warning/remark flags set and resolved. I've run all the MSVS 2013 tests that I know about and no signs arise.  I'm running a Win 10 Enterprise x64 version with all the patches applied. I have an Intel i7-4770 cpu running at 3.4GHz and 32GB of RAM. I have 3TB of disk storage and using only about 30% of that. Hardware is not a problem and even if I leaked like a sieve, I couldn't leak enough to stop it from working right off the bat. My project has 45 subroutines/procedures and I'm using a lot of heap space for arrays but I've set the heap size to a large number. I've uploaded a pdf of the screen at first startup.